NEET Chemistry Quick Reference
Periodic Table Key Data
ATOMIC RADIUS (pm):
Li(152) Na(186) K(227) | Be(112) Mg(160) Ca(197) | B(87) Al(143)
C(77) Si(118) | N(75) P(110) | O(73) S(103) | F(72) Cl(99)
IONISATION ENERGY (kJ/mol, first):
Trend: increases → across period | decreases ↓ down group
Exceptions: IE₁(B) < IE₁(Be) | IE₁(O) < IE₁(N) | IE₁(Tl) < IE₁(In)
ELECTRONEGATIVITY (Pauling scale):
F(3.98) O(3.44) N(3.04) Cl(3.16) Br(2.96) C(2.55) H(2.2) Na(0.93)
Important Reactions Quick Reference
IDENTIFICATION TESTS:
Primary amine: carbylamine test (CHCl₃ + KOH + R-NH₂ → isocyanide, foul smell)
Aldehyde: Tollens (silver mirror) | Fehling (red precipitate)
Ketone: 2,4-DNP (orange/red precipitate)
Unsaturation: decolourises Br₂/CCl₄
Phenol: FeCl₃ (violet colour) | doesn't react with NaHCO₃
Carboxylic acid: reacts with NaHCO₃ (CO₂ effervescence)
COLOUR GUIDE (inorganic — NEET loves these):
CrO₄²⁻: yellow | Cr₂O₇²⁻: orange | Cr³⁺: green | CrO₃: dark red
MnO₄⁻: purple | MnO₄²⁻: green | Mn²⁺: pink/light pink
Fe²⁺: pale green | Fe³⁺: yellow-brown | Cu²⁺: blue | Ni²⁺: green
FLAME TEST COLOURS:
Li: crimson red | Na: golden yellow | K: lilac/violet
Ca: brick red | Sr: crimson red | Ba: apple green | Cu: blue-green
Thermodynamics Key Formulas
ENTHALPY:
ΔH = ΔU + Δ(PV) = ΔU + ΔngRT (for ideal gases)
Hess's law: ΔH_rxn = ΣΔH_products - ΣΔH_reactants
ENTROPY AND GIBBS ENERGY:
ΔS > 0: disorder increases (solid→liquid→gas, dissolution, more moles of gas)
ΔG = ΔH - TΔS
ΔG < 0: spontaneous | ΔG > 0: non-spontaneous | ΔG = 0: equilibrium
THERMODYNAMIC PREDICTIONS:
ΔH < 0, ΔS > 0: always spontaneous (ΔG always negative)
ΔH > 0, ΔS < 0: never spontaneous
ΔH < 0, ΔS < 0: spontaneous at low T (enthalpy driven)
ΔH > 0, ΔS > 0: spontaneous at high T (entropy driven)
Electrochemistry Quick Reference
CELL REACTION AND EMF:
E°cell = E°cathode - E°anode (standard reduction potentials)
Positive E°cell → spontaneous reaction
NERNST EQUATION: E = E° - (0.0592/n) log Q (at 25°C)
At equilibrium: E = 0, so E° = (0.0592/n) log Keq
FARADAY'S LAWS:
Q = I × t (charge = current × time)
Mass deposited: m = (M × I × t) / (n × 96500)
1 Faraday = 96500 C = charge of 1 mole of electrons
CONDUCTANCE:
Specific conductance: κ = 1/ρ (reciprocal of resistivity)
Molar conductance: Λm = (κ × 1000) / M
Strong electrolytes: Λm increases linearly with dilution
Weak electrolytes: Λm increases sharply at high dilution (Kohlrausch law)