NEET Chemistry Fundamentals
Mole Concept and Stoichiometry
FUNDAMENTAL DEFINITIONS:
1 mole = 6.022 × 10²³ particles (Avogadro's number)
Molar mass = mass of 1 mole in grams = molecular weight
Moles = Mass (g) / Molar Mass (g/mol)
Moles = Number of particles / 6.022 × 10²³
Moles = Volume at STP (L) / 22.4 L/mol
STOICHIOMETRY STEPS:
1. Write balanced chemical equation
2. Convert given to moles
3. Use mole ratio from balanced equation
4. Convert to required units
PERCENTAGE COMPOSITION:
% of element = (atomic mass × number of atoms / molar mass) × 100
EMPIRICAL FORMULA:
% → grams (assume 100g) → moles → simplest ratio → empirical formula
Molecular formula: empirical × n where n = molar mass / empirical massPeriodic Table Fundamentals
PERIODS (horizontal rows): 7 periods
Valence electrons increase left to right
Atomic size decreases left to right
Ionisation energy increases left to right
Metallic character decreases left to right
GROUPS (vertical columns): 18 groups
s-block: groups 1-2 | d-block: groups 3-12 | p-block: groups 13-18
f-block: lanthanides and actinides
KEY TRENDS:
Atomic radius: increases down a group, decreases across a period
Ionisation energy: decreases down a group, increases across a period
Exceptions: IE₁(B) < IE₁(Be) and IE₁(O) < IE₁(N)
Electron affinity: increases across period (most negative for halogens)
Electronegativity: highest for F (3.98) | increases across period, decreases down group
IMPORTANT EXCEPTIONS:
Li resembles Mg (diagonal relationship) | Be resembles Al
Anomalous behaviour of first element of each groupChemical Bonding
IONIC BOND:
Metal + Non-metal | Metal loses electrons, non-metal gains
Crystal lattice | high melting point | conducts in solution or melt
Cation size < anion size (for typical ionic compounds)
COVALENT BOND:
Non-metal + Non-metal | electrons shared
Types: single (σ), double (σ+π), triple (σ+2π)
HYBRIDISATION (VSEPR for shape):
sp: linear 180° — BeCl₂, CO₂, C₂H₂
sp²: trigonal planar 120° — BF₃, SO₃, C₂H₄, graphite (each carbon)
sp³: tetrahedral 109.5° — CH₄, SiF₄, CCl₄ | 107° NH₃ | 104.5° H₂O
sp³d: trigonal bipyramidal — PCl₅ | sp³d²: octahedral — SF₆
BOND PROPERTIES:
Bond length: increases with bond order decrease | single > double > triple
Bond energy: increases with bond order | triple > double > single
Bond polarity: difference in electronegativityStudy Resources
•NCERT Chemistry Class 11 and 12 — absolutely mandatory for NEET
•MTG Fingertips Chemistry — quick revision format for NEET
•OP Tandon Physical Chemistry — for calculation-heavy topics
•NEET PYQ 2010-2024 Chemistry — identify repeat patterns

